Promoting effect of VDWGs-associated defect on CO2-to-CO catalysis a

Download scientific diagram | Promoting effect of VDWGs-associated defect on CO2-to-CO catalysis a C–O bond length and O–C–O bond angle of free CO2 (a1), CO2 adsorbed on VDWG-Bi-O-Bi (a2), and CO2 adsorbed on VDWG-Bi-VO••-Bi (a3). b1 Optimized geometric structures (parts containing charge density differences) and b2 schematic illustration of intermediates generated during CO2-to-CO catalysis over VDWG-Bi-VO••-Bi. c Gibbs free energy diagrams of intermediates generated during CO2-to-CO catalysis over VDWG-Bi-O-Bi and VDWG-Bi-VO••-Bi. d CO2-TPD of BOC-VDWGs-AL and BOC-VDWGs-AL-O2. e In situ FTIR of intermediates generated during pure-water PCR over BOC-VDWGs-AL. f Comparison of FTIR signal intensity of *CO intermediates from BOC-VDWGs-AL and BOC-VDWGs-AL-O2-driven pure-water PCR. g CO-TPD of BOC-VDWGs-AL and BOC-VDWGs-AL-O2. The VDWG-Bi-O-Bi was constructed by the calcination of VDWG-Bi-VO••-Bi (BOC-VDWGs-AL) under O2 atmonsphere. from publication: Van Der Waals gap-rich BiOCl atomic layers realizing efficient, pure-water CO2-to-CO photocatalysis | Photocatalytic CO2 reduction (PCR) is able to convert solar energy into chemicals, fuels, and feedstocks, but limited by the deficiencies of photocatalysts in steering photon-to-electron conversion and activating CO2, especially in pure water. Here we report an efficient, | Photocatalysis, Solar Fuels and Photocatalysts | ResearchGate, the professional network for scientists.

Yanqiang HUANG, Dalian Institute of Chemical Physics, Dalian, DICP

Yanqiang HUANG, Dalian Institute of Chemical Physics, Dalian, DICP

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Promoting effect of VDWGs-associated defect on CO2-to-CO catalysis a

Yanqiang HUANG, Dalian Institute of Chemical Physics, Dalian, DICP

Xiaobing Wang's research works Shaoguan University, Shaoguan (SGU) and other places

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